An illustration of a dramatic, herringbone-like pattern in the atomic lattice of a newly created quantum material. Against a black background, calcium atoms are seen as light blue spheres, cobalt atoms in dark blue and oxygen atoms in red. Lines connecting the oxygen atoms represent the atomic lattice.
February 22, 2023

SLAC, Stanford researchers make a new type of quantum material with a dramatic distortion pattern

Created by an electronic tug-of-war between the material’s atomic layers, this ‘beautiful’ herringbone-like pattern could give rise to unique features that scientists are just starting to explore.

 

By Glennda Chui

Researchers at the Department of Energy’s SLAC National Accelerator Laboratory and Stanford University have created a new type of quantum material whose atomic scaffolding, or lattice,  has been dramatically warped into a herringbone pattern.

The resulting distortions are “huge” compared to those achieved in other materials, said Woo Jin Kim, a postdoctoral researcher at the Stanford Institute for Materials and Energy Sciences (SIMES) at SLAC who led the study. 

“This is a very fundamental result, so it’s hard to make predictions about what may or may not come out of it, but the possibilities are exciting,” said SLAC/Stanford Professor and SIMES Director Harold Hwang. 

“Based on theoretical modeling from members of our team, it looks like the new material has intriguing magnetic, orbital and charge order properties that we plan to investigate further,” he said. Those are some of the very properties that scientists think give quantum materials their surprising characteristics. 

The research team described their work in a paper published in Nature today.

High-rises versus octahedrons

The herringbone-patterned material is the first demonstration of something called the Jahn-Teller (JT) effect in a layered material with a flat, planar lattice, like a high-rise building with evenly spaced floors.  

The JT effect addresses the dilemma an electron faces when it approaches an ion – an atom that’s missing one or more electrons. 

Just like a ball rolling along the ground will stop and settle in a low spot, the electron will seek out and occupy the vacancy in the atom’s electron orbitals that has the lowest energy state. But sometimes there are two vacancies with equally low energies. What then? 

If the ion is in a molecule or embedded in a crystal, the JT effect distorts the surrounding atomic lattice in a way that leaves only one vacancy at the lowest energy state, solving the electron’s problem, Hwang said. 

And when the whole crystal lattice consists of JT ions, in some cases the overall crystal structure warps, so the electron’s dilemma is cooperatively solved for all the ions. 

That’s what happened in this study.

A graphic shows how the atomic structure of a new quantum material is distorted by electronic forces between cobalt ions (dark blue) and oppositely charged calcium ions (light blue). This pushes the atoms closer together in two directions and pulls them apart in two other directions, resulting in a herringbone-like structure.
Illustration showing distortions in a new quantum material that were produced by an electronic tug-of-war between negatively charged cobalt ions ­and positively charged calcium ions. In what’s known as the Jahn-Teller effect, each cobalt ion tries to pull calcium ions from the layers above and below it, warping the atomic lattice in the direction of the arrows in a way that had not been seen before.    (Woo Jin Kim/SIMES)

“The Jahn-Teller effect creates strong interactions between the electrons and between the electrons and the lattice,” Hwang said. “This is thought to play key roles in the physics of a number of quantum materials.” 

The JT effect had already been demonstrated for single molecules and for 3D crystalline materials that consist of ions arranged in octahedral or tetrahedral structures. In fact, JT oxides based on manganese or copper exhibit colossal magnetoresistance and high-temperature superconductivity – leading scientists to wonder what would happen in materials based on other elements or having a different structure.

In this study, the SIMES researchers turned a material made of cobalt, calcium and oxygen (CaCoO2.5), which has a different stacking of octahedral and tetrahedral layers and is known as brownmillerite,  into a layered material (CaCoO2) where the JT effect could take hold. They did it with a chemical trick developed at SIMES a few years ago to make the first nickel oxide superconductor.

Pulling out Jenga blocks

Kim synthesized a thin film of brownmillerite and chemically removed single layers of oxygen atoms from its lattice, much like players carefully remove blocks from a Jenga tower. The lattice collapsed and settled into a flat, planar configuration with alternating layers containing negatively charged cobalt ions ­– the JT ions ­– and positively charged calcium ions. 

: Two depictions of atomic structures appear against a white background. At left, layers of octahedral molecules alternative with layers of tetrahedral molecules. After layers of oxygen atoms are chemically removed, the structure collapses into the one at right, which is like a high-rise building with evenly spaced floors that contain cobalt ions (dark blue) and calcium atoms (light blue).
In experiments at SLAC and Stanford, researchers changed the atomic structure of the material at left, which consists of octahedral and tetrahedral layers and is known as brownmillerite,  by chemically removing layers of oxygen, much as Jenga players carefully removed wooden blocks from a stack. The resulting material, right, was dramatically distorted into a herringbone pattern by an electronic tug-of-war between its layers caused by the Jahn-Teller effect. ( Woo Jin Kim/SIMES)

Each cobalt ion tried to pull calcium ions from the layers above and below it, Kim said. 

“This tug-of-war between adjacent layers led to a beautiful pattern of distortions that reflects the best and most harmonious compromise between the forces at play,” he said. “And the resulting lattice distortions are huge compared to those in other materials ­– equal to 25% of the distance between ions in the lattice.”

Hwang said the research team will be exploring this remarkable new electronic configuration with X-ray tools available at SLAC and elsewhere. “We also wonder what will happen if we can dope this material – replacing some atoms with others to change the number of electrons that are free to move around,” he said. “There are many exciting possibilities.”

Researchers from Cornell University, the Pohang Accelerator Laboratory in South Korea and the Center for Nanoscale Materials Sciences, a DOE Office of Science user facility at Oak Ridge National Laboratory, contributed to this work. It received major funding from the DOE Office of Science and the Gordon and Betty Moore Foundation’s Emergent Phenomena in Quantum Systems Initiative. 

Citation: Woo Jin Kim et al., Nature, 22 February 2023 (10.1038/s41586-022-05681-2)

For questions or comments, contact the SLAC Office of Communications at communications@slac.stanford.edu.


About SLAC

SLAC National Accelerator Laboratory explores how the universe works at the biggest, smallest and fastest scales and invents powerful tools used by researchers around the globe. As world leaders in ultrafast science and bold explorers of the physics of the universe, we forge new ground in understanding our origins and building a healthier and more sustainable future. Our discovery and innovation help develop new materials and chemical processes and open unprecedented views of the cosmos and life’s most delicate machinery. Building on more than 60 years of visionary research, we help shape the future by advancing areas such as quantum technology, scientific computing and the development of next-generation accelerators.

SLAC is operated by Stanford University for the U.S. Department of Energy’s Office of Science. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States and is working to address some of the most pressing challenges of our time.

Dig Deeper

Related stories

News Brief

A SLAC study shows a process called atomic relaxation offers a new way to explore quantum states in these puzzling materials.

Light blue wavy lines on a maroon red background.
News Feature

SLAC partners with five national labs and eight universities seeking to increase the supply diversity of EV batteries and relieve supply chain concerns.

SLAC-Stanford Battery Center
News Feature

An associate scientist at SSRL, Richardson studies plant growth to find ways to enhance nutrient uptake in plants, especially in challenging conditions – such...

Jocelyn Richardson
News Brief

A SLAC study shows a process called atomic relaxation offers a new way to explore quantum states in these puzzling materials.

Light blue wavy lines on a maroon red background.
News Feature

SLAC partners with five national labs and eight universities seeking to increase the supply diversity of EV batteries and relieve supply chain concerns.

SLAC-Stanford Battery Center
News Feature

An associate scientist at SSRL, Richardson studies plant growth to find ways to enhance nutrient uptake in plants, especially in challenging conditions – such...

Jocelyn Richardson
News Feature

Descamps was recognized for turning the world’s most powerful X-ray laser into a sophisticated tool for probing extremely hot, dense matter.

Adrien Descamps presents his research.
News Brief

The SLAC professor was elected to the American Physical Society in recognition of his research on ultrafast X-ray methods.

Kelly Gaffney
News Feature

An energy systems engineer, Cezar helps bridge advanced energy research and applications.

Portrait of Gustavo Cezar